Unknown

Dataset Information

0

Bis{?-2-[(2-oxidobenzyl-idene)amino-meth-yl]phenolato-?O,N,O'}bis-[(pyridine-?N)zinc(II)].

ABSTRACT: In the title centrosymmetric zinc(II) complex, [Zn(2)(C(4)H(13)NO(2))(2)(C(6)H(5)N)(2)], each Zn(II) atom is coordinated by two 2-[(2-oxidobenzyl-idene)amino-meth-yl]phenolate (L) ligands and one pyridine (py) mol-ecule in a distorted trigonal-bipyramidal geometry. Each L ligand behaves as a tridentate ligand and provides a phenolate oxygen bridge which links the two Zn(II) atoms. The ZnL(py) units are linked by ?-? inter-actions between adjacent pyridine mol-ecules, with a centroid-centroid distance of 3.724?Å, resulting in a two-dimensional structure.

SUBMITTER: Yang C 

PROVIDER: S-EPMC2960381 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Bis{μ-2-[(2-oxidobenzyl-idene)amino-meth-yl]phenolato-κO,N,O'}bis-[(pyridine-κN)zinc(II)].

Yang Chun C   Yan Ou-Yang OY   Wang Qing-Lun QL   Liao Dai-Zheng DZ  

Acta crystallographica. Section E, Structure reports online 20080116 Pt 2

In the title centrosymmetric zinc(II) complex, [Zn(2)(C(4)H(13)NO(2))(2)(C(6)H(5)N)(2)], each Zn(II) atom is coordinated by two 2-[(2-oxidobenzyl-idene)amino-meth-yl]phenolate (L) ligands and one pyridine (py) mol-ecule in a distorted trigonal-bipyramidal geometry. Each L ligand behaves as a tridentate ligand and provides a phenolate oxygen bridge which links the two Zn(II) atoms. The ZnL(py) units are linked by π-π inter-actions between adjacent pyridine mol-ecules, with a centroid-centroid dis  ...[more]

Similar Datasets

Unknown Bis(?-2-{bis-[(2-oxidobenzyl-idene)amino]-meth-yl}phenolato)bis-[(tetra-hydro-furan)-samarium(III)] tetra-hydro-furan disolvate.
| S-EPMC3344343 | biostudies-literature
Unknown Bis{2-[3-(dimethyl-amino)propyl-imino-meth-yl]-4,6-dihydro-seleno-phenolato}zinc(II).
| S-EPMC2969977 | biostudies-literature
Unknown Bis{?-2-[2-(2-pyrid-yl)ethyl-imino-meth-yl]phenolato}bis-[azido-zinc(II)].
| S-EPMC2961521 | biostudies-literature
Unknown (2-{[1-(Pyridin-2-yl)ethyl-idene]amino-meth-yl}pyridine-?N,N',N'')bis-(thio-cyanato-?N)zinc.
| S-EPMC3247537 | biostudies-literature
Unknown Bis{5-meth-oxy-2-[(1H-pyrrol-2-yl)methyl-imino-meth-yl]phenolato}zinc(II).
| S-EPMC2970064 | biostudies-literature
Unknown Bis{2-[(2-furylmeth-yl)imino-meth-yl]-5-meth-oxy-phenolato-?N,O}zinc(II).
| S-EPMC3099774 | biostudies-literature
Unknown Bis[2-(cyclo-propyl-imino-meth-yl)-5-methoxy-phenolato]zinc(II).
| S-EPMC2979218 | biostudies-literature
Unknown Bis{2-meth-oxy-6-[3-(methyl-amino)propyl-imino-meth-yl]phenolato}nickel(II) bis-(perchlorate).
| S-EPMC2961174 | biostudies-literature
Unknown Bis{2-[3-(dimethyl-amino)-propyl-imino-meth-yl]-6-meth-oxy-phenolato}-?N,N',O;?N,O-zinc(II) dihydrate.
| S-EPMC3050366 | biostudies-literature
Unknown Bis{2-[(1H-pyrrol-2-yl)methyl-imino-meth-yl]phenolato-κN,O}zinc(II).
| S-EPMC2969913 | biostudies-literature