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Bis{?-2-[(2-oxidobenzyl-idene)amino-meth-yl]phenolato-?O,N,O'}bis-[(pyridine-?N)zinc(II)].

ABSTRACT: In the title centrosymmetric zinc(II) complex, [Zn(2)(C(4)H(13)NO(2))(2)(C(6)H(5)N)(2)], each Zn(II) atom is coordinated by two 2-[(2-oxidobenzyl-idene)amino-meth-yl]phenolate (L) ligands and one pyridine (py) mol-ecule in a distorted trigonal-bipyramidal geometry. Each L ligand behaves as a tridentate ligand and provides a phenolate oxygen bridge which links the two Zn(II) atoms. The ZnL(py) units are linked by ?-? inter-actions between adjacent pyridine mol-ecules, with a centroid-centroid distance of 3.724?Å, resulting in a two-dimensional structure.

SUBMITTER: Yang C

PROVIDER: S-EPMC2960381 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

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Bis{μ-2-[(2-oxidobenzyl-idene)amino-meth-yl]phenolato-κO,N,O'}bis-[(pyridine-κN)zinc(II)].

Yang Chun C Yan Ou-Yang OY Wang Qing-Lun QL Liao Dai-Zheng DZ

Acta crystallographica. Section E, Structure reports online 20080116 Pt 2

In the title centrosymmetric zinc(II) complex, [Zn(2)(C(4)H(13)NO(2))(2)(C(6)H(5)N)(2)], each Zn(II) atom is coordinated by two 2-[(2-oxidobenzyl-idene)amino-meth-yl]phenolate (L) ligands and one pyridine (py) mol-ecule in a distorted trigonal-bipyramidal geometry. Each L ligand behaves as a tridentate ligand and provides a phenolate oxygen bridge which links the two Zn(II) atoms. The ZnL(py) units are linked by π-π inter-actions between adjacent pyridine mol-ecules, with a centroid-centroid dis ...[more]

PMID: 21201321

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