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[4-(Methoxy-carbon-yl)benz-yl]triphenyl-phospho-nium bromide hemihydrate.

ABSTRACT: In the crystal structure of the title compound, C(27)H(24)O(2)P(+)·Br(-)·0.5H(2)O, there are inter-molecular O-H?Br hydrogen bonds between the H atoms of the water of crystallization and the bromide anions. The three phenyl rings of the triphenyl-phosphonium moiety are at angles of 59.73?(15), 79.15?(14) and 82.81?(17)° with the C/P/C planes.

SUBMITTER: Nazir S

PROVIDER: S-EPMC2960404 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

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[4-(Methoxy-carbon-yl)benz-yl]triphenyl-phospho-nium bromide hemihydrate.

Nazir Saba S Khawar Rauf M M Ebihara Masahiro M Hameed Shahid S

Acta crystallographica. Section E, Structure reports online 20080111 Pt 2

In the crystal structure of the title compound, C(27)H(24)O(2)P(+)·Br(-)·0.5H(2)O, there are inter-molecular O-H⋯Br hydrogen bonds between the H atoms of the water of crystallization and the bromide anions. The three phenyl rings of the triphenyl-phosphonium moiety are at angles of 59.73 (15), 79.15 (14) and 82.81 (17)° with the C/P/C planes. ...[more]

PMID: 21201450

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