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(4-Methoxy-benzoyl-meth-yl)triphenyl-phospho-nium trifluoro-methane-sulfonate.

ABSTRACT: Colourless crystals of the title compound, C(27)H(24)O(2)P(+)·CF(3)SO(3) (-), have been prepared by the addition of a solution of AgCF(3)SO(3) in methanol to a solution of (4-methoxy-benzoyl-meth-yl)triphenyl-phospho-nium bromide in dry methanol. There are two crystallographically independent mol-ecules in the asymmetric unit. The crystal structure is stabilized by inter- and intra-molecular C-H?O hydrogen bonds and further stabilized by C-H?? inter-actions.

SUBMITTER: Karami K

PROVIDER: S-EPMC2968230 | biostudies-literature | 2009 Jan

REPOSITORIES: biostudies-literature

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(4-Methoxy-benzoyl-meth-yl)triphenyl-phospho-nium trifluoro-methane-sulfonate.

Karami Kazem K Büyükgüngör Orhan O

Acta crystallographica. Section E, Structure reports online 20090114 Pt 2

Colourless crystals of the title compound, C(27)H(24)O(2)P(+)·CF(3)SO(3) (-), have been prepared by the addition of a solution of AgCF(3)SO(3) in methanol to a solution of (4-methoxy-benzoyl-meth-yl)triphenyl-phospho-nium bromide in dry methanol. There are two crystallographically independent mol-ecules in the asymmetric unit. The crystal structure is stabilized by inter- and intra-molecular C-H⋯O hydrogen bonds and further stabilized by C-H⋯π inter-actions. ...[more]

PMID: 21581906

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