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Poly[[diaqua-?(2)-4,4'-bipyridyl-?(2)-o-phthalato-nickel(II)] dihydrate].

ABSTRACT: In the title layer complex, {[Ni(C(8)H(4)O(4))(C(10)H(8)N(2))(H(2)O)(2)]·2H(2)O}(n), the Ni atom has a distorted octa-hedral environment, defined by the phthalate and 4,4'-bipyridyl ligands which link the Ni atoms, forming a square lattice in the bc plane. This extends into a three-dimensional supra-molecular network through O-H?O hydrogen-bonding inter-actions. The Ni atom lies on, and both ligands are bis-ected by, a crystallographic twofold axis.

SUBMITTER: Zhang X

PROVIDER: S-EPMC2960449 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

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Poly[[diaqua-μ(2)-4,4'-bipyridyl-μ(2)-o-phthalato-nickel(II)] dihydrate].

Zhang Xiao X Yi Zhihui Z Xia Wujiong W Yang Chao C Li Bing B

Acta crystallographica. Section E, Structure reports online 20080116 Pt 2

In the title layer complex, {[Ni(C(8)H(4)O(4))(C(10)H(8)N(2))(H(2)O)(2)]·2H(2)O}(n), the Ni atom has a distorted octa-hedral environment, defined by the phthalate and 4,4'-bipyridyl ligands which link the Ni atoms, forming a square lattice in the bc plane. This extends into a three-dimensional supra-molecular network through O-H⋯O hydrogen-bonding inter-actions. The Ni atom lies on, and both ligands are bis-ected by, a crystallographic twofold axis. ...[more]

PMID: 21201307

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