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Dichlorido(dimethyl-formamide-?O)[1,4,7-tris-(2-cyano-ethyl)-1,4,7-triaza-cyclo-nonane-?N,N,N]nickel(II).

ABSTRACT: The title complex, [NiCl(2)(C(15)H(24)N(6))(C(3)H(7)NO)], is isomorphous with the Co(II) analogue. Three N-atom donors from the facially coordinating triaza macrocyclic ligand, one O-atom donor from dimethyl-formamide and two Cl(-) anions surround the Ni(II) ion in a distorted octa-hedral coordination geometry. Inter-molecular C-H?Cl and C-H?N hydrogen-bonding inter-actions link the complex mol-ecules into a three-dimensional supra-molecular architecture.

SUBMITTER: Zhang Z

PROVIDER: S-EPMC2960500 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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Dichlorido(dimethyl-formamide-κO)[1,4,7-tris-(2-cyano-ethyl)-1,4,7-triaza-cyclo-nonane-κN,N,N]nickel(II).

Zhang Zhong Z Wu Li-Zhen LZ Geng Zhi-Rong ZR Wang Zhi-Lin ZL

Acta crystallographica. Section E, Structure reports online 20080806 Pt 9

The title complex, [NiCl(2)(C(15)H(24)N(6))(C(3)H(7)NO)], is isomorphous with the Co(II) analogue. Three N-atom donors from the facially coordinating triaza macrocyclic ligand, one O-atom donor from dimethyl-formamide and two Cl(-) anions surround the Ni(II) ion in a distorted octa-hedral coordination geometry. Inter-molecular C-H⋯Cl and C-H⋯N hydrogen-bonding inter-actions link the complex mol-ecules into a three-dimensional supra-molecular architecture. ...[more]

PMID: 21201578

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