Browse
Submit Data
Databases
API
Help

Dataset Information

30 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

(2,2'-Bipyridine-?N,N')chlorido(1,4,7-trithia-cyclo-nonane-?S,S',S'')ruthenium(II) nitrate monohydrate.

ABSTRACT: In the title compound, [RuCl(C(10)H(8)N(2))(C(6)H(12)S(3))]NO(3)·H(2)O or [RuCl(bpy)([9]aneS(3))]NO(3)·H(2)O, ([9]aneS(3) is 1,4,7-tri-thia-cyclo-nonane and bpy is 2,2'-bipyridine), the Ru(II) cation has a slightly distorted octa-hedral environment composed of three facially coordinated S atoms from ([9]aneS(3)), two N atoms from bpy and a chloride anion. The nitrate counter-ion and the water mol-ecule of crystallization are engaged in O-H?O hydrogen-bonding inter-actions, leading to a supra-molecular chain running parallel to the c axis.

SUBMITTER: Fernandes JA

PROVIDER: S-EPMC3011741 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

(2,2'-Bipyridine-κN,N')chlorido(1,4,7-trithia-cyclo-nonane-κS,S',S'')ruthenium(II) nitrate monohydrate.

Fernandes José A JA Almeida Paz Filipe A FA Mota Maria João P MJ Braga Susana S SS Santos Teresa M TM

Acta crystallographica. Section E, Structure reports online 20101113 Pt 12

In the title compound, [RuCl(C(10)H(8)N(2))(C(6)H(12)S(3))]NO(3)·H(2)O or [RuCl(bpy)([9]aneS(3))]NO(3)·H(2)O, ([9]aneS(3) is 1,4,7-tri-thia-cyclo-nonane and bpy is 2,2'-bipyridine), the Ru(II) cation has a slightly distorted octa-hedral environment composed of three facially coordinated S atoms from ([9]aneS(3)), two N atoms from bpy and a chloride anion. The nitrate counter-ion and the water mol-ecule of crystallization are engaged in O-H⋯O hydrogen-bonding inter-actions, leading to a supra-mol ...[more]

PMID: 21589261

Similar Datasets

(2,2'-Bipyridine-?N,N')bromido(1,4,7-trithia-cyclo-nonane-?S,S',S'')ruthenium(II) hexa-fluoridophosphate.

Project description:The title compound, [RuBr(C(10)H(8)N(2))(C(6)H(12)S(3))]PF(6) or [RuBr(bpy)([9]aneS(3))]PF(6) ([9]aneS(3) is 1,4,7-trithia-cyclo-nonane and bpy is 2,2'-bipyridine), exhibits a very similar octahedral coordination geometry for the Ru(2+) atom to that of its [RuCl(bpy)([9]aneS(3))](+) analogue, with only the chloride ligand being substituted by a bromide ligand. The presence of a PF(6) (-) anion (alongside with the coordinated bromide ligand) promotes the existence of an extensive network of weak C-H?X (X = F, Br) inter-actions.

| S-EPMC3051521 | biostudies-other

Triaqua-(1,4,7-triaza-cyclo-nonane-?N,N,N)nickel(II) bromide nitrate.

Project description:In the title half-sandwich compound, [Ni(C(6)H(15)N(3))(H(2)O)(3)]Br(NO(3)), the central Ni(II) ion, lying on a threefold rotation axis, is six-coordinated by three amine N atoms from the face-capping triaza macrocycle and three water O atoms in a slightly distorted octa-hedral geometry. In the crystal, O-H?O hydrogen bonding and weak O-H?Br inter-actions associate the Ni(II) cations and the counter-ions into a three-dimensional supra-molecular network.

| S-EPMC2979567 | biostudies-literature

(2,2'-Bipyridine-4,4'-dicarb-oxy-lic acid-?N,N')chlorido(2,2':6',2''-terpyridyl-?N,N',N'')ruthenium(II) perchlorate ethanol monosolvate monohydrate.

Project description:In the title compound, [RuCl(C(15)H(11)N(3))(C(12)H(8)N(2)O(4))]ClO(4)·C(2)H(5)OH·H(2)O, the geometry of the ClN(5) coordination set around the Ru(II) atom is close to octa-hedral, but distorted on account of the limited bite angles of the polypyridyl ligands. The complexes are linked by O-H?O hydrogen bonds between the carboxyl groups and the crystal lattice water mol-ecules into chains along [110]. Face-to-face stacking inter-actions are formed between terpyridine ligands, with inter-planar separations of 3.66?(1) and 3.42?(1)?Å, and between bipyridine-4,4'-dicarb-oxy-lic acid ligands, with inter-planar separations of 3.65?(1) and 3.72?(1)?Å. Three O atoms of the perchlorate ion are each disordered equally over two positions. The hy-droxy group of the ethanol mol-ecule is also disordered over two sites with refined occupancies of 0.794?(9) and 0.206?(9).

| S-EPMC3254339 | biostudies-literature

Dichlorido(dimethyl-formamide-?O)[1,4,7-tris-(2-cyano-ethyl)-1,4,7-triaza-cyclo-nonane-?N,N,N]nickel(II).

Project description:The title complex, [NiCl(2)(C(15)H(24)N(6))(C(3)H(7)NO)], is isomorphous with the Co(II) analogue. Three N-atom donors from the facially coordinating triaza macrocyclic ligand, one O-atom donor from dimethyl-formamide and two Cl(-) anions surround the Ni(II) ion in a distorted octa-hedral coordination geometry. Inter-molecular C-H?Cl and C-H?N hydrogen-bonding inter-actions link the complex mol-ecules into a three-dimensional supra-molecular architecture.

| S-EPMC2960500 | biostudies-literature

Dichlorido(dimethyl-formamide-κO)[1,4,7-tris-(2-cyano-ethyl)-1,4,7-triaza-cyclo-nonane-κN,N,N]cobalt(II).

Project description:The title compound, [CoCl(2)(C(15)H(24)N(6))(C(3)H(7)NO)], crystallizes as a monomeric complex. The coordination environment around the Co(II) center could be described as a distorted octa-hedron consisting of three N donors from the facially coordinating triaza macrocyclic ligand, one O donor from dimethyl-formamide and two Cl(-) ions. Neutral complex mol-ecules are associated via inter-molecular C-H⋯Cl hydrogen bonds to form two-dimensional layers. C-H⋯O hydrogen bonds are also present.

| S-EPMC2961961 | biostudies-literature

Bis(2,2'-bipyridine)(5,5'-imino-ditetra-zolato)cadmium(II) 2,2'-bipyridine hemisolvate monohydrate.

Project description:The title complex, [Cd(C(2)HN(9))(C(10)H(8)N(2))(2)]·0.5C(10)H(8)N(2)·H(2)O, was prepared under hydro-thermal reaction conditions. The asymmetric unit contains the cadmium complex, half a 2,2'-bipyridine solvent mol-ecule and a solvent water mol-ecule. The Cd(II) ion is coordinated by four N atoms from two 2,2'-bipyridine ligands and two N atoms from an HBTA(-) anion ligand [where H(2)BTA is N,N-bis-(1H-tetra-zol-5-yl)amine], forming an octa-hedral geometry. The complex is linked into a three-dimensional network by O-H?N and N-H?N hydrogen bonds and by the stacking inter-actions of rings, with distances of 3.5-3.7?Å between the atoms of two parallel 2,2'-bipyridine rings.

| S-EPMC2915158 | biostudies-literature

Tris(propionitrile-κN)[1,4,7-tris-(cyano-meth-yl)-1,4,7-triaza-cyclo-nonane-κN,N,N]copper(II) bis-(perchlorate) dihydrate.

Project description:In the title compound, [Cu(C(3)H(5)N)(3)(C(12)H(18)N(6))](ClO(4))(2)·2H(2)O, the Cu(II) atom lies on a threefold rotation axis and is coordinated in a distorted N(6) octa-hedral environment by three tertiary amines from the tridentate chelating aza-macrocyclic ligand and three propionitrile mol-ecules. Inter-molecular non-classical C-H⋯N hydrogen bonding inter-links the [Cu(C(3)H(5)N)(3)(C(12)H(18)N(6))](2+) cations into a two-dimensional supra-molecular sheet extending along the ab plane. The crystal packing also exhibits weak C-H⋯O inter-actions.

| S-EPMC2979962 | biostudies-literature

Di-?-chlorido-bis-[aqua-(2,2'-bipyridine-?N,N')chloridocobalt(II)].

Project description:The title complex, [Co(2)Cl(4)(C(10)H(8)N(2))(2)(H(2)O)(2)], is composed of two Co(II) atoms, each hexa-coordinated by three Cl atoms, one 2,2'-bipyridine (bpy) ligand and one water mol-ecule in a distorted octa-hedral geometry. Neighboring Co(II) atoms are linked together by two Cl bridges, forming a dinuclear Co(II) complex with inversion symmetry. There are inter-molecular O-H?Cl hydrogen bonds and inter-molecular ?-? stacking inter-actions between adjacent bpy ligands [centroid-centroid distance = 3.617?(2)?Å] in the structure.

| S-EPMC2977247 | biostudies-literature

(2,2'-Bipyridine-κN,N')chlorido[4'-(2,5-dimethoxy-phen-yl)-2,2':6',2''-terpyridine-κN,N',N'']ruthenium(II) hexa-fluorido-phosphate acetonitrile monosolvate.

Project description:In the title compound, [RuCl(C(10)H(8)N(2))(C(23)H(19)N(3)O(2))]PF(6)·CH(3)CN, the ligand environment about the Ru(II) atom is distorted octa-hedral, with the substituted terpyridyl ligand coordinated in a meridional fashion, the bipyridyl ligand coordinated in a cis fashion and the Cl atom trans to one of the bipyridyl N atoms. The Ru-N distances are in the range 2.036 (2)-2.084 (2) Å with the exception of the central Ru-N bond from the terpyridyl ligand, which is shorter [1.9503 (19) Å], as expected. The pendant dimethoxy-phenyl substituent is not coplanar with the terpyridyl unit; the dihedral angle between the central pyridyl ring and the benzene ring is 46.72 (11)°. The anion is disordered equally over two positions around an F-P-F bond axis.

| S-EPMC2969997 | biostudies-literature

Bis(2,2'-bipyridine)(2-hy-droxy-2,2-diphenyl-acetato)-copper(II) nitrate dihydrate.

Project description:In the title complex, [Cu(C(14)H(11)O(3))(C(10)H(8)N(2))(2)]NO(3)·2H(2)O, the Cu(II) atom is coordinated by four N atoms from two 2,2'-bipyridine ligands and two O atoms from one benzilate ligand in a distorted octa-hedral geometry. A supra-molecular network is formed via inter-molecular O-H?O and C-H?O hydrogen-bonding inter-actions. ?-? stacking inter-actions between neighboring pyridine rings are also present, the centroid-centroid distance being 3.808?(2)?Å.

| S-EPMC2983227 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data