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Barium zinc diarsenate.

ABSTRACT: The title compound, BaZnAs(2)O(7), belongs to the family of isotypic series of compounds adopting the general formula M1(2+)M2(2+)X(2)O(7) (M1(2+) = Ca, Sr, Ba or Pb; M2(2+) = Mg, Cr, Mn, Fe, Co, Ni, Cu, Zn or Cd; X = P or As). Suitable single crystals were prepared under hydro-thermal conditions. The framework structure is characterized by corner-sharing ZnO(5) square pyramids and As(2)O(7) groups where the Zn atoms occupy channels. X-ray diffraction analysis of single crystals twinned by non-merohedry [twin plane is (100)] yielded formula BaZnAs(2)O(7). Raman spectra confirmed the presence of a non-linear As-O-As linkage.

SUBMITTER: Dordevic T

PROVIDER: S-EPMC2960529 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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Barium zinc diarsenate.

Dordević Tamara T

Acta crystallographica. Section E, Structure reports online 20080809 Pt 9

The title compound, BaZnAs(2)O(7), belongs to the family of isotypic series of compounds adopting the general formula M1(2+)M2(2+)X(2)O(7) (M1(2+) = Ca, Sr, Ba or Pb; M2(2+) = Mg, Cr, Mn, Fe, Co, Ni, Cu, Zn or Cd; X = P or As). Suitable single crystals were prepared under hydro-thermal conditions. The framework structure is characterized by corner-sharing ZnO(5) square pyramids and As(2)O(7) groups where the Zn atoms occupy channels. X-ray diffraction analysis of single crystals twinned by non-m ...[more]

PMID: 21201565

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