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Poly[aqua-[?-N'-(carboxymethyl)ethylene-diamine--N,N,N'-triacetato]neodymium(III)].

ABSTRACT: In the title complex, [Nd(C(10)H(13)N(2)O(8))(H(2)O)](n), each Nd(III) ion is coordinated by six O atoms and two N atoms from one N'-(carboxymethyl)ethylene-diamine--N,N,N'-triacetate (edta) ligand and one water mol-ecule, displaying a bicapped trigonal-prismatic geometry. The edta ligands link the neodymium metal centres, forming polymeric chains running along the a axis of the unit cell. These chains are further assembled via inter-molecular O-H?O hydrogen-bonding inter-actions into a three-dimensional supra-molecular network.

SUBMITTER: Huang XH

PROVIDER: S-EPMC2960570 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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Poly[aqua-[μ-N'-(carboxymethyl)ethylene-diamine--N,N,N'-triacetato]neodymium(III)].

Huang Xiao-Hui XH Xu Xiao-Hong XH Pan Wei-Bo WB Zeng Rong-Hua RH

Acta crystallographica. Section E, Structure reports online 20080823 Pt 9

In the title complex, [Nd(C(10)H(13)N(2)O(8))(H(2)O)](n), each Nd(III) ion is coordinated by six O atoms and two N atoms from one N'-(carboxymethyl)ethylene-diamine--N,N,N'-triacetate (edta) ligand and one water mol-ecule, displaying a bicapped trigonal-prismatic geometry. The edta ligands link the neodymium metal centres, forming polymeric chains running along the a axis of the unit cell. These chains are further assembled via inter-molecular O-H⋯O hydrogen-bonding inter-actions into a three-di ...[more]

PMID: 21201633

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