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Trans-Aqua-(4,7-diaza-decane-1,10-diamine-?N)fluoridochromium(III) bis-(perchlorate) monohydrate.

ABSTRACT: In the title compound, [CrF(C(8)H(20)N(4))(H(2)O)](ClO(4))(2)·H(2)O, the Cr atom is in a slightly distorted octa-hedral environment, coordinated by four N atoms of the 4,7-diaza-decane-1,10-diamine ligand, one water mol-ecule and an F atom trans to water. The five-membered chelate ring is in a gauche form, while the two six-membered chelate rings are in chair conformations. The crystal structure is stabilized by several hydrogen bonds.

SUBMITTER: Choi JH

PROVIDER: S-EPMC2960685 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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trans-Aqua-(4,7-diaza-decane-1,10-diamine-κN)fluoridochromium(III) bis-(perchlorate) monohydrate.

Choi Jong-Ha JH Lee Uk U

Acta crystallographica. Section E, Structure reports online 20080820 Pt 9

In the title compound, [CrF(C(8)H(20)N(4))(H(2)O)](ClO(4))(2)·H(2)O, the Cr atom is in a slightly distorted octa-hedral environment, coordinated by four N atoms of the 4,7-diaza-decane-1,10-diamine ligand, one water mol-ecule and an F atom trans to water. The five-membered chelate ring is in a gauche form, while the two six-membered chelate rings are in chair conformations. The crystal structure is stabilized by several hydrogen bonds. ...[more]

PMID: 21201626

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