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Tetra-?-2,5-difluoro-benzoato-bis-[(2,2'-bipyridine)(2,5-difluoro-benzoato)gadolinium(III)].

ABSTRACT: In the centrosymmetric title compound, [Gd(2)(C(7)H(3)F(2)O(2))(6)(C(10)H(8)N(2))(2)], the asymmetric unit comprises one cation chelated by two 2,5-difluoro-benzoate and one 2,2'-bipyridine. Two cations are linked into dimers via three bridging carboxyl-ate groups from three 2,5-difluoro-benzoic acid units. The Gd(III) ion is nine-coord-inated by seven O atoms and two N atoms.

SUBMITTER: Li S 

PROVIDER: S-EPMC2960618 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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Tetra-μ-2,5-difluoro-benzoato-bis-[(2,2'-bipyridine)(2,5-difluoro-benzoato)gadolinium(III)].

Li Sheng S   Zhang Fu-Li FL   Tang Kun K   Ma Yuan-Fang YF  

Acta crystallographica. Section E, Structure reports online 20080809 Pt 9

In the centrosymmetric title compound, [Gd(2)(C(7)H(3)F(2)O(2))(6)(C(10)H(8)N(2))(2)], the asymmetric unit comprises one cation chelated by two 2,5-difluoro-benzoate and one 2,2'-bipyridine. Two cations are linked into dimers via three bridging carboxyl-ate groups from three 2,5-difluoro-benzoic acid units. The Gd(III) ion is nine-coord-inated by seven O atoms and two N atoms. ...[more]

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