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Ethyl 2-(2-methyl-1H-benzimidazol-1-yl)acetate.

ABSTRACT: A new benzimidazole compound, C(12)H(14)N(2)O(2), has been synthesized by the reaction of 2-methyl-1H-benzimidazole and ethyl 2-bromo-acetate. In the crystal structure, weak inter-molecular C-H?N hydrogen bonds link the mol-ecules into chains. ??? Contacts (centroid?centroid distance = 3.713?Å) are observed. A C-H?? inter-action is also present. The N-C-C-O torsion angle is 178.4?(2)°.

SUBMITTER: Xu GH

PROVIDER: S-EPMC2960733 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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Ethyl 2-(2-methyl-1H-benzimidazol-1-yl)acetate.

Xu Guang-Hai GH Wang Wei W

Acta crystallographica. Section E, Structure reports online 20080823 Pt 9

A new benzimidazole compound, C(12)H(14)N(2)O(2), has been synthesized by the reaction of 2-methyl-1H-benzimidazole and ethyl 2-bromo-acetate. In the crystal structure, weak inter-molecular C-H⋯N hydrogen bonds link the mol-ecules into chains. π⋯π Contacts (centroid⋯centroid distance = 3.713 Å) are observed. A C-H⋯π inter-action is also present. The N-C-C-O torsion angle is 178.4 (2)°. ...[more]

PMID: 21201788

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