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Bis{[(?)-cyclopentadienyl]tris(diethyl phosphito-?P,P',P'')cobaltate(III)-?O,O',O'']oxovanadium(IV)}-?-oxalate.

ABSTRACT: The title compound {systematic name: bis[1,4(?(5))-cyclo-penta-dien-yl]hexa-kis(?-diethyl phosphito)-1:2?(6)P:O;3:4?(6)O:P-?-ox-alato-2:3?(4)O(1),O(2):O(1'),O(2')-dioxido-2?O,3?O-1,4-dicobalt(III)-2,3-divanadium(IV)}, [Co(2)V(2)(C(5)H(5))(2)(C(2)O(4))(C(4)H(10)O(3)P)(6)O(2)], is an oxalate-bridged dinuclear complex of oxovanadium(IV). The geometric center of the dimer lies on an inversion center. The unique Co atom is bonded to three P atoms and a cyclo-penta-dienyl ring. The unique V atom has six O atom neighbors in an approximately octa-hedral arrangement; the V-O bond trans to the V=O bond is significantly lengthened.

SUBMITTER: McLauchlan CC 

PROVIDER: S-EPMC2960739 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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Bis{[(η)-cyclopentadienyl]tris(diethyl phosphito-κP,P',P'')cobaltate(III)-κO,O',O'']oxovanadium(IV)}-μ-oxalate.

McLauchlan Craig C CC   Anderson Alexander E AE  

Acta crystallographica. Section E, Structure reports online 20080806 Pt 9

The title compound {systematic name: bis[1,4(η(5))-cyclo-penta-dien-yl]hexa-kis(μ-diethyl phosphito)-1:2κ(6)P:O;3:4κ(6)O:P-μ-ox-alato-2:3κ(4)O(1),O(2):O(1'),O(2')-dioxido-2κO,3κO-1,4-dicobalt(III)-2,3-divanadium(IV)}, [Co(2)V(2)(C(5)H(5))(2)(C(2)O(4))(C(4)H(10)O(3)P)(6)O(2)], is an oxalate-bridged dinuclear complex of oxovanadium(IV). The geometric center of the dimer lies on an inversion center. The unique Co atom is bonded to three P atoms and a cyclo-penta-dienyl ring. The unique V atom has s  ...[more]

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