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Imidazolium trans-bis-(imino-diacetato-?O,N,O')cobaltate(III).

ABSTRACT: In the title compound, (C(3)H(5)N(2))[Co(C(4)H(5)NO(4))(2)], the cation and anion are located on a twofold rotation axis and inversion center, respectively. Inter-molecular N-H?O hydrogen bonds link the cations and anions into layers parallel to the ab plane. The crystal packing also exhibits weak C-H?O hydrogen bonds, including bifurcated hydrogen bonds, and C=O?? inter-actions.

SUBMITTER: Gao XL

PROVIDER: S-EPMC2977607 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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Imidazolium trans-bis-(imino-diacetato-κO,N,O')cobaltate(III).

Gao Xiao-Li XL Lu Li-Ping LP Zhu Miao-Li ML

Acta crystallographica. Section E, Structure reports online 20090425 Pt 5

In the title compound, (C(3)H(5)N(2))[Co(C(4)H(5)NO(4))(2)], the cation and anion are located on a twofold rotation axis and inversion center, respectively. Inter-molecular N-H⋯O hydrogen bonds link the cations and anions into layers parallel to the ab plane. The crystal packing also exhibits weak C-H⋯O hydrogen bonds, including bifurcated hydrogen bonds, and C=O⋯π inter-actions. ...[more]

PMID: 21583793

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