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N'-(3-Thienylmethyl-ene)pyridine-2-carbohydrazide.

ABSTRACT: The title compound, C(11)H(9)N(3)OS, was prepared to investigate the coordination chemistry of thio-phene-containing ligands as precursors to inter-esting metallopolymers. The mol-ecule is nearly planar. The angle between the thio-phene and pyridine rings is 8.63?(4)° and features the expected trans configuration about the imine bond. The structure is stabilized by a weak inter-molecular N-H?O hydrogen bond. The distance between centroids of adjacent thio-phene rings [3.67?(8)?Å] suggests the presence of ?-? inter-actions.

SUBMITTER: Cheng H 

PROVIDER: S-EPMC2961063 | biostudies-literature | 2008 Mar

REPOSITORIES: biostudies-literature

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N'-(3-Thienylmethyl-ene)pyridine-2-carbohydrazide.

Cheng Haojin H   Djukic Brandon B   Harrington Laura E LE   Britten James F JF   Lemaire Martin T MT  

Acta crystallographica. Section E, Structure reports online 20080314 Pt 4

The title compound, C(11)H(9)N(3)OS, was prepared to investigate the coordination chemistry of thio-phene-containing ligands as precursors to inter-esting metallopolymers. The mol-ecule is nearly planar. The angle between the thio-phene and pyridine rings is 8.63 (4)° and features the expected trans configuration about the imine bond. The structure is stabilized by a weak inter-molecular N-H⋯O hydrogen bond. The distance between centroids of adjacent thio-phene rings [3.67 (8) Å] suggests the pr  ...[more]

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