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Di-?-thio-cyanato-bis-({2,4-dichloro-6-[2-(diethyl-amino)ethyl-imino-meth-yl]phenolato}copper(II)).

ABSTRACT: The title compound, [Cu(2)(NCS)(2)(C(13)H(17)Cl(2)N(2)O)(2)], was obtained by the reaction of 3,5-dichloro-salicylaldehyde, N,N-diethyl-ethane-1,2-diamine, sodium thio-cyanate, and copper(II) acetate in an ethanol solution. It crystallizes as a centrosymmetric dimer with a very long Cu?S axial bond [2.972?(3)?Å]. The Cu atom is five-coordinated by the three donor atoms of the Schiff base ligand, 2,4-dichloro-6-[(2-diethyl-amino-ethyl-imino)meth-yl]phenol, one N atom of a thio-cyanate group, and one S atom of a symmetry-related thio-cyanate group, forming a slightly distorted square-pyramidal geometry.

SUBMITTER: Li XW 

PROVIDER: S-EPMC2915145 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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Di-μ-thio-cyanato-bis-({2,4-dichloro-6-[2-(diethyl-amino)ethyl-imino-meth-yl]phenolato}copper(II)).

Li Xian-Wen XW   Qiu Yang Y  

Acta crystallographica. Section E, Structure reports online 20071218 Pt 1

The title compound, [Cu(2)(NCS)(2)(C(13)H(17)Cl(2)N(2)O)(2)], was obtained by the reaction of 3,5-dichloro-salicylaldehyde, N,N-diethyl-ethane-1,2-diamine, sodium thio-cyanate, and copper(II) acetate in an ethanol solution. It crystallizes as a centrosymmetric dimer with a very long Cu⋯S axial bond [2.972 (3) Å]. The Cu atom is five-coordinated by the three donor atoms of the Schiff base ligand, 2,4-dichloro-6-[(2-diethyl-amino-ethyl-imino)meth-yl]phenol, one N atom of a thio-cyanate group, and  ...[more]

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