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Poly[diaqua-?(2)-oxalato-di-?(2)-pyrimidine-2-carboxyl-ato-dimanganese(II)].

ABSTRACT: In the title compound, [Mn(2)(C(2)O(4))(C(5)H(3)N(2)O(2))(2)(H(2)O)(2)](n), the Mn(II) atom exhibits a distorted octa-hedral coordination geometry, with the centrosymmetric oxalate anion and the monoanionic pyrimidine-2-carboxyl-ate ligands generating a two-dimensional honeycomb network with a (6,3)-topology.

SUBMITTER: Rodriguez-Dieguez A

PROVIDER: S-EPMC2961100 | biostudies-literature | 2008 Apr

REPOSITORIES: biostudies-literature

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Poly[diaqua-μ(2)-oxalato-di-μ(2)-pyrimidine-2-carboxyl-ato-dimanganese(II)].

Rodríguez-Diéguez Antonio A Aouryaghal Hakima H Mota A J AJ Colacio Enrique E

Acta crystallographica. Section E, Structure reports online 20080402 Pt 5

In the title compound, [Mn(2)(C(2)O(4))(C(5)H(3)N(2)O(2))(2)(H(2)O)(2)](n), the Mn(II) atom exhibits a distorted octa-hedral coordination geometry, with the centrosymmetric oxalate anion and the monoanionic pyrimidine-2-carboxyl-ate ligands generating a two-dimensional honeycomb network with a (6,3)-topology. ...[more]

PMID: 21202173

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