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2,2'-(Imino-dimethyl-ene)dibenz-imid-azol-ium bis-(perchlorate) methanol solvate.

ABSTRACT: In the title compound, C(16)H(17)N(5) (2+)·2ClO(4) (-)·CH(3)OH, the dihedral angle between the two benzimidazolium ring systems is 34.6?(1)°. The anions and solvent mol-ecules are linked to the cation by N-H?O hydrogen bonds. In the crystal structure, the combination of N-H?O and O-H?O hydrogen bonds results in two-dimensional layers running parallel to the (010) plane; these are in turn linked by ?-? inter-actions, forming a three-dimensional network.

SUBMITTER: Zhou CS

PROVIDER: S-EPMC2961233 | biostudies-literature | 2008 Apr

REPOSITORIES: biostudies-literature

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2,2'-(Imino-dimethyl-ene)dibenz-imid-azol-ium bis-(perchlorate) methanol solvate.

Zhou Chun-Shan CS Huang Xue-Ying XY Meng Xiang-Gao XG

Acta crystallographica. Section E, Structure reports online 20080402 Pt 5

In the title compound, C(16)H(17)N(5) (2+)·2ClO(4) (-)·CH(3)OH, the dihedral angle between the two benzimidazolium ring systems is 34.6 (1)°. The anions and solvent mol-ecules are linked to the cation by N-H⋯O hydrogen bonds. In the crystal structure, the combination of N-H⋯O and O-H⋯O hydrogen bonds results in two-dimensional layers running parallel to the (010) plane; these are in turn linked by π-π inter-actions, forming a three-dimensional network. ...[more]

PMID: 21202284

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