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Catena-Poly[[diaqua-manganese(II)]-di-?-pyridine-3-sulfonato-?N:O;?O:N].

ABSTRACT: In the title polymeric complex, [Mn(C(5)H(4)NO(3)S)(2)(H(2)O)(2)](n), the Mn atom is located on a centre of inversion and is coordinated by two O atoms and two N atoms derived from four different pyridine-3-sulfonate (pySO(3)) ligands, and two O atoms derived from two water mol-ecules in a distorted trans-N(2)O(4) octa-hedral geometry. The metal atoms are bridged by the pySO(3) ligands to form a one-dimensional chain. The chains are further connected into a three-dimensional architecture via hydrogen bonds.

SUBMITTER: Qiu ZH

PROVIDER: S-EPMC2961366 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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catena-Poly[[diaqua-manganese(II)]-di-μ-pyridine-3-sulfonato-κN:O;κO:N].

Qiu Zhi-Hui ZH Liang Fu-Pei FP Ruan Qing-Feng QF Zhao Shan-Rong SR

Acta crystallographica. Section E, Structure reports online 20080503 Pt 6

In the title polymeric complex, [Mn(C(5)H(4)NO(3)S)(2)(H(2)O)(2)](n), the Mn atom is located on a centre of inversion and is coordinated by two O atoms and two N atoms derived from four different pyridine-3-sulfonate (pySO(3)) ligands, and two O atoms derived from two water mol-ecules in a distorted trans-N(2)O(4) octa-hedral geometry. The metal atoms are bridged by the pySO(3) ligands to form a one-dimensional chain. The chains are further connected into a three-dimensional architecture via hyd ...[more]

PMID: 21202458

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catena-Poly[[[diaqua-nickel(II)]-di-?-glycine] dichloride].

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Project description:The title complex, [Co(C(5)H(4)NO(3)S)(2)(H(2)O)(2)], lies on a twofold rotation axis that relates the two water mol-ecules and the two pyridine-2-sulfonate ions. The Co(II) atom exists in an slightly distorted octa-hedral environment. The N-donor atoms are cis to each other. In the crystal, adjacent mol-ecules are linked by O-H?O hydrogen bonds into a layer motif extending along (001).

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catena-Poly[[diaqua-bis-(3-methyl-pyridine-?N)cobalt(II)]-?-sulfato-?O:O'].

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