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Diaqua-bis-(pyridine-2-sulfonato-?N,O)cobalt(II).

ABSTRACT: The title complex, [Co(C(5)H(4)NO(3)S)(2)(H(2)O)(2)], lies on a twofold rotation axis that relates the two water mol-ecules and the two pyridine-2-sulfonate ions. The Co(II) atom exists in an slightly distorted octa-hedral environment. The N-donor atoms are cis to each other. In the crystal, adjacent mol-ecules are linked by O-H?O hydrogen bonds into a layer motif extending along (001).

SUBMITTER: Li ZS

PROVIDER: S-EPMC3238694 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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Diaqua-bis-(pyridine-2-sulfonato-κN,O)cobalt(II).

Li Zong-Sheng ZS Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20111119 Pt 12

The title complex, [Co(C(5)H(4)NO(3)S)(2)(H(2)O)(2)], lies on a twofold rotation axis that relates the two water mol-ecules and the two pyridine-2-sulfonate ions. The Co(II) atom exists in an slightly distorted octa-hedral environment. The N-donor atoms are cis to each other. In the crystal, adjacent mol-ecules are linked by O-H⋯O hydrogen bonds into a layer motif extending along (001). ...[more]

PMID: 22199571

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