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Dichloridobis(di-tert-butyl-methyl-phosphine oxide-?O)diphenyl-tin(IV).

ABSTRACT: The complete mol-ecule of the title compound, [Sn(C(6)H(5))(2)Cl(2)(C(9)H(21)OP)(2)], is generated by crystallographic inversion symmetry, the Sn atom is located on a special position of site symmetry . The Sn atom adopts an all-trans SnC(2)O(2)Cl(2) octa-hedral geometry. As a consequence of the bulky substituents at the O atom, the P-O-Sn bond angle is 163.9?(3)°.

SUBMITTER: Muller M

PROVIDER: S-EPMC2961504 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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Dichloridobis(di-tert-butyl-methyl-phosphine oxide-κO)diphenyl-tin(IV).

Müller Manuela M Lerner Hans-Wolfram HW Bolte Michael M

Acta crystallographica. Section E, Structure reports online 20080510 Pt 6

The complete mol-ecule of the title compound, [Sn(C(6)H(5))(2)Cl(2)(C(9)H(21)OP)(2)], is generated by crystallographic inversion symmetry, the Sn atom is located on a special position of site symmetry . The Sn atom adopts an all-trans SnC(2)O(2)Cl(2) octa-hedral geometry. As a consequence of the bulky substituents at the O atom, the P-O-Sn bond angle is 163.9 (3)°. ...[more]

PMID: 21202490

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