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Tetra-iodido[methyl-enebis(diphenyl-phosphine oxide)-?O:O']tin(IV) chloro-form solvate.

ABSTRACT: The title compound, [SnI(4)(C(25)H(22)O(2)P(2))]·CHCl(3), crystallized from a chloro-form solution of SnI(4) and the diphosphine CH(2)(PPh(2))(2) exposed to air. The monomeric complex displays a distorted octa-hedral coordinaton for the tin(IV) atom with average Sn-I and Sn-O bond lengths of 2.79?(2) and 2.15?(1)?Å, respectively.

SUBMITTER: Caldwell AM

PROVIDER: S-EPMC2961740 | biostudies-literature | 2008 Jun

REPOSITORIES: biostudies-literature

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Tetra-iodido[methyl-enebis(diphenyl-phosphine oxide)-κO:O']tin(IV) chloro-form solvate.

Caldwell Allison M AM Tanski Joseph M JM

Acta crystallographica. Section E, Structure reports online 20080607 Pt 7

The title compound, [SnI(4)(C(25)H(22)O(2)P(2))]·CHCl(3), crystallized from a chloro-form solution of SnI(4) and the diphosphine CH(2)(PPh(2))(2) exposed to air. The monomeric complex displays a distorted octa-hedral coordinaton for the tin(IV) atom with average Sn-I and Sn-O bond lengths of 2.79 (2) and 2.15 (1) Å, respectively. ...[more]

PMID: 21202760

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