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Crystal structure of tert-butyl-diphenyl-phosphine oxide.

ABSTRACT: In the structure of the title triorganophosphine oxide, C16H19OP, the P-O bond is 1.490?(1)?Å. The P atom has a distorted tetrahedral geometry. The O atom inter-acts with both phenyl groups of a neighboring mol-ecule [C?O = 2.930?(3) and 2.928?(4)?Å]. The C-O interaction directs an extended supramolecular arrangement along the a-axis.

SUBMITTER: Agbeworvi G

PROVIDER: S-EPMC4459331 | biostudies-literature | 2015 Jun

REPOSITORIES: biostudies-literature

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Crystal structure of tert-butyl-diphenyl-phosphine oxide.

Agbeworvi George G Assefa Zerihun Z Sykora Richard E RE Taylor Jared D JD

Acta crystallographica. Section E, Crystallographic communications 20150513 Pt 6

In the structure of the title triorganophosphine oxide, C16H19OP, the P-O bond is 1.490 (1) Å. The P atom has a distorted tetrahedral geometry. The O atom inter-acts with both phenyl groups of a neighboring mol-ecule [C⋯O = 2.930 (3) and 2.928 (4) Å]. The C-O interaction directs an extended supramolecular arrangement along the a-axis. ...[more]

PMID: 26090188

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