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Bis{?-2-[2-(2-pyrid-yl)ethyl-imino-meth-yl]phenolato}bis-[azido-zinc(II)].

ABSTRACT: In the centrosymmetric title dinuclear zinc(II) compound, [Zn(2)(C(14)H(13)N(2)O)(2)(N(3))(2)], each Zn(II) ion has a slightly distorted trigonal bipyramidal geometry and is coordinated by two N atoms and one O atom from one Schiff base ligand, an O atom from the other Schiff base ligand, and another N atom from an azide ligand. The crystal structure involves inter-molecular C-H?N hydrogen bonds.

SUBMITTER: Zhou XR

PROVIDER: S-EPMC2961521 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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Bis{μ-2-[2-(2-pyrid-yl)ethyl-imino-meth-yl]phenolato}bis-[azido-zinc(II)].

Zhou Xiang-Rong XR Li Zhong-Shu ZS Zhang Lei L Zhou Zhi-Hong ZH

Acta crystallographica. Section E, Structure reports online 20080510 Pt 6

In the centrosymmetric title dinuclear zinc(II) compound, [Zn(2)(C(14)H(13)N(2)O)(2)(N(3))(2)], each Zn(II) ion has a slightly distorted trigonal bipyramidal geometry and is coordinated by two N atoms and one O atom from one Schiff base ligand, an O atom from the other Schiff base ligand, and another N atom from an azide ligand. The crystal structure involves inter-molecular C-H⋯N hydrogen bonds. ...[more]

PMID: 21202480

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