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8-Bromo-naphthalen-1-amine.

ABSTRACT: The title compound, C(10)H(8)BrN, was obtained by slow addition of sodium azide to 8-bromo-1-naphthoic acid, followed by addition of aqueous ammonia. The crude product was crystallized from petroleum ether to give pink crystals. Compared to other 1,8-disubstituted naphthalene compounds, this compound exhibits less strain between the 1 and 8 substituents. Additionally, the NH protons form both intra- and inter-molecular hydrogen bonds. The naphthalene units are arranged in a herring-bone stacking motif.

SUBMITTER: Fuller AL 

PROVIDER: S-EPMC2961535 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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8-Bromo-naphthalen-1-amine.

Fuller Amy L AL   Knight Fergus R FR   Slawin Alexandra M Z AM   Woollins J Derek JD  

Acta crystallographica. Section E, Structure reports online 20080503 Pt 6

The title compound, C(10)H(8)BrN, was obtained by slow addition of sodium azide to 8-bromo-1-naphthoic acid, followed by addition of aqueous ammonia. The crude product was crystallized from petroleum ether to give pink crystals. Compared to other 1,8-disubstituted naphthalene compounds, this compound exhibits less strain between the 1 and 8 substituents. Additionally, the NH protons form both intra- and inter-molecular hydrogen bonds. The naphthalene units are arranged in a herring-bone stacking  ...[more]

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