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(Thio-cyanato-?N)bis-(thio-semicarbazide-?S)copper(I).

ABSTRACT: In the title complex, [Cu(CH(5)N(3)S)(2)(NCS)], the non-H part of the mol-ecule is strictly planar, lying on the mirror plane at y = 0.25. The Cu atom lies at the centre of a triangle formed by the coordination of three monodentate groups, viz. two thio-semicarbazide ligands and one NCS(-) anion. Weak inter-molecular N-H?S inter-actions generate a two-dimensional network.

SUBMITTER: Jia L 

PROVIDER: S-EPMC2961608 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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(Thio-cyanato-κN)bis-(thio-semicarbazide-κS)copper(I).

Jia Li L   Ma Shouxin S   Li Dacheng D  

Acta crystallographica. Section E, Structure reports online 20080510 Pt 6

In the title complex, [Cu(CH(5)N(3)S)(2)(NCS)], the non-H part of the mol-ecule is strictly planar, lying on the mirror plane at y = 0.25. The Cu atom lies at the centre of a triangle formed by the coordination of three monodentate groups, viz. two thio-semicarbazide ligands and one NCS(-) anion. Weak inter-molecular N-H⋯S inter-actions generate a two-dimensional network. ...[more]

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