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Aqua-bis(nicotinamide-?N)(thio-cyanato-?N)copper(II).

ABSTRACT: In the title compound, [Cu(NCS)(2)(C(6)H(6)N(2)O)(2)(H(2)O)], the Cu atom adopts a square-based pyramidal CuN(4)O coordination, with the water O atom in the apical position. The pairs of N-bonded nicotinamide ligands and thio-cyanate anions in the basal plane are in a trans configuration. In the crystal structure, the mol-ecules are connected into sheets by N-H?O and O-H?O hydrogen bonds.

SUBMITTER: Li C

PROVIDER: S-EPMC2960236 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

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Aqua-bis(nicotinamide-κN)(thio-cyanato-κN)copper(II).

Li Chunyuan C Ding Weijia W Shao Changlun C

Acta crystallographica. Section E, Structure reports online 20080109 Pt 2

In the title compound, [Cu(NCS)(2)(C(6)H(6)N(2)O)(2)(H(2)O)], the Cu atom adopts a square-based pyramidal CuN(4)O coordination, with the water O atom in the apical position. The pairs of N-bonded nicotinamide ligands and thio-cyanate anions in the basal plane are in a trans configuration. In the crystal structure, the mol-ecules are connected into sheets by N-H⋯O and O-H⋯O hydrogen bonds. ...[more]

PMID: 21201285

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