Ontology highlight
ABSTRACT:
SUBMITTER: Karan NK
PROVIDER: S-EPMC2977581 | biostudies-literature | 2009 Apr
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20090418 Pt 5
In the title complex, [Cu(NCS)(2)(C(6)H(8)N(2))(2)], the Cu(II) atom, lying on an inversion center, adopts a Jahn-Teller distorted octahedral CuN(6) coordination geometry. The two bidentate 2-amino-methyl-pyridine ligands are coordinated in a trans fashion, while the two thio-cyanate ligands are at the axial positions and coordinate to the Cu atom in a bent mode with a C-N-Cu angle of 127.49 (10)°. Inter-molecular N-H⋯N and N-H⋯S hydrogen bonds link the copper complex mol-ecules into an infinite ...[more]