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Bis[2-(amino-meth-yl)pyridine-?N,N']bis-(thio-cyanato-?N)copper(II).


ABSTRACT: In the title complex, [Cu(NCS)(2)(C(6)H(8)N(2))(2)], the Cu(II) atom, lying on an inversion center, adopts a Jahn-Teller distorted octahedral CuN(6) coordination geometry. The two bidentate 2-amino-methyl-pyridine ligands are coordinated in a trans fashion, while the two thio-cyanate ligands are at the axial positions and coordinate to the Cu atom in a bent mode with a C-N-Cu angle of 127.49?(10)°. Inter-molecular N-H?N and N-H?S hydrogen bonds link the copper complex mol-ecules into an infinite two-dimensional network.

SUBMITTER: Karan NK 

PROVIDER: S-EPMC2977581 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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Bis[2-(amino-meth-yl)pyridine-κN,N']bis-(thio-cyanato-κN)copper(II).

Karan Nirmal Kumar NK   Chan Kai-Ting KT   Lee Hon Man HM  

Acta crystallographica. Section E, Structure reports online 20090418 Pt 5


In the title complex, [Cu(NCS)(2)(C(6)H(8)N(2))(2)], the Cu(II) atom, lying on an inversion center, adopts a Jahn-Teller distorted octahedral CuN(6) coordination geometry. The two bidentate 2-amino-methyl-pyridine ligands are coordinated in a trans fashion, while the two thio-cyanate ligands are at the axial positions and coordinate to the Cu atom in a bent mode with a C-N-Cu angle of 127.49 (10)°. Inter-molecular N-H⋯N and N-H⋯S hydrogen bonds link the copper complex mol-ecules into an infinite  ...[more]

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