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Tetra-chloridobis(dibenzyl sulfoxide-?O)tin(IV).

ABSTRACT: The six-coordinate Sn(IV) atom in the title compound, [SnCl(4)(C(14)H(14)OS)(2)], exists in a cis-SnCl(4)O(2) octa-hedral geometry. Of the four Cl atoms, two are close to adjacent S atoms [Cl?S = 3.320?(1) and 3.376?(1)?Å]; the Sn-Cl bonds involving these two Cl atoms are longer than the other two Sn-Cl bonds.

SUBMITTER: Keng TC

PROVIDER: S-EPMC3120392 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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Tetra-chloridobis(dibenzyl sulfoxide-κO)tin(IV).

Keng Thy Chun TC Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20110507 Pt 6

The six-coordinate Sn(IV) atom in the title compound, [SnCl(4)(C(14)H(14)OS)(2)], exists in a cis-SnCl(4)O(2) octa-hedral geometry. Of the four Cl atoms, two are close to adjacent S atoms [Cl⋯S = 3.320 (1) and 3.376 (1) Å]; the Sn-Cl bonds involving these two Cl atoms are longer than the other two Sn-Cl bonds. ...[more]

PMID: 21754572

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