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Tetra-kis(?-4-ethyl-benzoato-?O:O')-bis-[(4-ethyl-benzoic acid-?O)copper(II)].

ABSTRACT: The molecule of the title compound, [Cu(2)(C(9)H(9)O(2))(4)(C(9)H(10)O(2))(2)], lies on a center of inversion. It consists of four bridging ethyl-benzoate ligands, forming a cage around two Cu atoms in a syn-syn configuration, and two monodentate ethyl-benzoic acid ligands bonded apically to the square-planar Cu atoms. The Cu?Cu distance is 2.6047?(5)?Å.

SUBMITTER: Sunil AC

PROVIDER: S-EPMC2961780 | biostudies-literature | 2008 Jun

REPOSITORIES: biostudies-literature

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Tetra-kis(μ-4-ethyl-benzoato-κO:O')-bis-[(4-ethyl-benzoic acid-κO)copper(II)].

Sunil Abraham C AC Bezuidenhoudt Barend C B BC Janse van Rensburg J Marthinus JM

Acta crystallographica. Section E, Structure reports online 20080619 Pt 7

The molecule of the title compound, [Cu(2)(C(9)H(9)O(2))(4)(C(9)H(10)O(2))(2)], lies on a center of inversion. It consists of four bridging ethyl-benzoate ligands, forming a cage around two Cu atoms in a syn-syn configuration, and two monodentate ethyl-benzoic acid ligands bonded apically to the square-planar Cu atoms. The Cu⋯Cu distance is 2.6047 (5) Å. ...[more]

PMID: 21202792

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