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Tetra-kis(?-4-azido-benzoato-?O:O')bis-[(N,N-dimethyl-formamide-?O)copper(II)].

ABSTRACT: The binuclear title compound, [Cu(2)(C(7)H(4)N(3)O(2))(4)(C(3)H(7)NO)(2)], is a discrete metal-organic compound having a paddle-wheel-type structure. The Cu?Cu distance is 2.6366?(5)?Å and an inversion center is located at the mid-point of this bond. The Cu(II) cation is coordinated by four carboxyl-ate O atoms from four 4-azido-benzoate ligands, and one O atom from a dimethyl-formamide mol-ecule, forming an overall distorted octahedral geometry when the Cu?Cu bond is also considered.

SUBMITTER: Wang A

PROVIDER: S-EPMC3254312 | biostudies-literature | 2012 Jan

REPOSITORIES: biostudies-literature

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Tetra-kis(μ-4-azido-benzoato-κO:O')bis-[(N,N-dimethyl-formamide-κO)copper(II)].

Wang Aidong A

Acta crystallographica. Section E, Structure reports online 20111214 Pt 1

The binuclear title compound, [Cu(2)(C(7)H(4)N(3)O(2))(4)(C(3)H(7)NO)(2)], is a discrete metal-organic compound having a paddle-wheel-type structure. The Cu⋯Cu distance is 2.6366 (5) Å and an inversion center is located at the mid-point of this bond. The Cu(II) cation is coordinated by four carboxyl-ate O atoms from four 4-azido-benzoate ligands, and one O atom from a dimethyl-formamide mol-ecule, forming an overall distorted octahedral geometry when the Cu⋯Cu bond is also considered. ...[more]

PMID: 22259343

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