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Bis(5-chloro-salicylato-?O)bis-(1,10-phenanthroline-?N,N')cadmium(II).

ABSTRACT: In the title complex, [Cd(C(7)H(4)ClO(3))(2)(C(12)H(8)N(2))(2)], the Cd atom is coordinated by two 5-chloro-salicylate ligands and two 1,10-phenanthroline ligands, displaying a distorted octa-hedral coordination geometry. The crystal structure is stabilized by O-H?O and C-H?O hydrogen bonds and ?-? inter-actions between the 1,10-phenanthroline ligands and 5-chloro-salicylate ligands, with a centroid-centroid distance between neighbouring aromatic rings of 3.730?(1)?Å.

SUBMITTER: Wen D 

PROVIDER: S-EPMC2961793 | biostudies-literature | 2008 Jun

REPOSITORIES: biostudies-literature

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Bis(5-chloro-salicylato-κO)bis-(1,10-phenanthroline-κN,N')cadmium(II).

Wen Decai D   Xie Jing J   Jiang Xiurong X  

Acta crystallographica. Section E, Structure reports online 20080607 Pt 7

In the title complex, [Cd(C(7)H(4)ClO(3))(2)(C(12)H(8)N(2))(2)], the Cd atom is coordinated by two 5-chloro-salicylate ligands and two 1,10-phenanthroline ligands, displaying a distorted octa-hedral coordination geometry. The crystal structure is stabilized by O-H⋯O and C-H⋯O hydrogen bonds and π-π inter-actions between the 1,10-phenanthroline ligands and 5-chloro-salicylate ligands, with a centroid-centroid distance between neighbouring aromatic rings of 3.730 (1) Å. ...[more]

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