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(Croconato-?O,O')bis-(1,10-phenanthroline-?N,N')zinc(II).

ABSTRACT: In the title compound, [Zn(C(5)O(5))(C(12)H(8)N(2))(2)], the Zn atom is in a slightly distorted octa-hedral environment. The mol-ecule lies across a twofold rotation axis, around which two 1,10-phenanthroline ligands are arranged. There are short contacts between the 1,10-phenanthroline groups and the O atoms of the croconate ligand, which probably stabilize the crystal structure via weak C-H?O interactions.

SUBMITTER: Chen H

PROVIDER: S-EPMC2960028 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature

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(Croconato-κO,O')bis-(1,10-phenanthroline-κN,N')zinc(II).

Chen Hongyu H Li Ping P Dong Lihua L Zhu Xiaohui X Fang Qi Q

Acta crystallographica. Section E, Structure reports online 20081108 Pt 12

In the title compound, [Zn(C(5)O(5))(C(12)H(8)N(2))(2)], the Zn atom is in a slightly distorted octa-hedral environment. The mol-ecule lies across a twofold rotation axis, around which two 1,10-phenanthroline ligands are arranged. There are short contacts between the 1,10-phenanthroline groups and the O atoms of the croconate ligand, which probably stabilize the crystal structure via weak C-H⋯O interactions. ...[more]

PMID: 21581127

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Aqua-bis-(benzoato-?O)(1,10-phenanthroline-?N,N')zinc(II).

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