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(E)-1-Ferrocenyl-3-phenyl-prop-2-en-1-one.

ABSTRACT: The title compound, [Fe(C(5)H(5))(C(14)H(11)O)], exists as the E isomer, and the substituent is fully conjugated with the attached five-membered ring. In the ferrocene unit, the substituted cyclo-penta-dienyl ring (Cps) plane and unsubstituted cyclo-penta-dienyl ring (Cp) plane are almost parallel, and the C atoms in Cp and Cps are in an eclipsed conformation. In the crystal structure, mol-ecules are linked into C(5) chains via inter-molecular C-H⋯O hydrogen bonds, and neighbouring chains are assembled into sheets by inter-molecular C-H⋯π(arene) hydrogen bonds along the c axis.

SUBMITTER: Liu YH

PROVIDER: S-EPMC2961926 | biostudies-literature |

REPOSITORIES: biostudies-literature

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(E)-1-Ferrocenyl-3-(3-nitro-phen-yl)prop-2-en-1-one.

Project description:In the title compound, [Fe(C(5)H(5))(C(14)H(10)NO(3))], one cyclo-penta-diene ring is substituted and one is unsubstituted. The two rings are almost parallel and are eclipsed and ordered. The conjugated substituent is slightly twisted with respect to the cyclo-penta-diene ring. The crystal structure contains four inter-molecular C-H?O hydrogen-bonds in the range 3.324?(3)-3.539?(3)?Å and one ?(aryl ring)-? (Cp ring) stacking inter-action with a ring-centroid distance of 3.894?(2)?Å.

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(E)-1-Ferrocenyl-3-(2-fur-yl)prop-2-en-1-one.

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(E)-3-Ferrocenyl-1-(2-hy-droxy-phen-yl)-prop-2-en-1-one.

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