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Di-μ-chlorido-bis-{[2-(morpholinometh-yl)phenyl-κC,N]palladium(II)}.

ABSTRACT: The title compound, [Pd(2)(C(11)H(14)NO)(2)Cl(2)], has a dimeric structure with Cl atoms bridging the two Pd atoms, one half of the mol-ecule being generated by symmetry due to the crystallographic inversion centre located in the middle of the perfectly planar Pd(2)Cl(2) ring. The five-membered ring adopts an envelope conformation, while the morpholino group has a chair conformation. The geometry around the metal centres is distorted square-planar, as a result of a strong intra-molecular N→Pd coordination trans to a Pd-Cl bond. In the crystal structure, the dimeric structure is strengthened by inter-molecular C-H⋯Cl hydrogen bonds. C-H⋯C(phen-yl) inter-actions link the dimers into a columnar supra-molecular array along the a axis; the dimers are further connected by C-H⋯Ph inter-actions into a three-dimensional supra-molecular arrangement.

SUBMITTER: Copolovici D

PROVIDER: S-EPMC2961971 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

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Di-μ-chlorido-bis-{[2-(morpholinometh-yl)phenyl-κC,N]palladium(II)}.

Copolovici Dana D Silvestru Cristian C Isaia Francesco F Varga Richard A RA

Acta crystallographica. Section E, Structure reports online 20080723 Pt 8

The title compound, [Pd(2)(C(11)H(14)NO)(2)Cl(2)], has a dimeric structure with Cl atoms bridging the two Pd atoms, one half of the mol-ecule being generated by symmetry due to the crystallographic inversion centre located in the middle of the perfectly planar Pd(2)Cl(2) ring. The five-membered ring adopts an envelope conformation, while the morpholino group has a chair conformation. The geometry around the metal centres is distorted square-planar, as a result of a strong intra-molecular N→Pd co ...[more]

PMID: 21203041

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