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Trans-Di-?-acetato-?O:O'-bis-[2-(5-phenyl-isoxazolin-3-yl)phenyl-?C,N]dipalladium(II).

ABSTRACT: The title compound, [Pd(2)(C(15)H(10)NO)(2)(C(2)H(3)O(2))(2)], crystallized from a dichloro-methane/n-hexane solution with two crystallographically independent dimeric mol-ecules in the asymmetric unit. Each mol-ecule may be described as a dimer with an anti configuration and the cyclo-metallated fragments in the characteristic open-book disposition, linked by two bridging acetate ligands.

SUBMITTER: Zhou J

PROVIDER: S-EPMC2961565 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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trans-Di-μ-acetato-κO:O'-bis-[2-(5-phenyl-isoxazolin-3-yl)phenyl-κC,N]dipalladium(II).

Zhou Jin J Wang Qibao Q Sun Hongjian H

Acta crystallographica. Section E, Structure reports online 20080517 Pt 6

The title compound, [Pd(2)(C(15)H(10)NO)(2)(C(2)H(3)O(2))(2)], crystallized from a dichloro-methane/n-hexane solution with two crystallographically independent dimeric mol-ecules in the asymmetric unit. Each mol-ecule may be described as a dimer with an anti configuration and the cyclo-metallated fragments in the characteristic open-book disposition, linked by two bridging acetate ligands. ...[more]

PMID: 21202504

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Di-μ-acetato-κO:O'-bis-{[2-(2-pyrid-yl)phenyl-κC,N]palladium(II)}.

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Di-μ-acetato-κO:O-bis-{(acetato-κO,O')bis-[3-(1H-imidazol-1-yl-κN)-1-phenyl-propan-1-one]cadmium} tetra-hydrate.

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Di-μ-chlorido-bis-{[2-(morpholinometh-yl)phenyl-κC,N]palladium(II)}.

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Poly[bis-(μ(4)-acetato-κO:O:O':O')bis-(μ(3)-acetato-κO:O:O)(μ(2)-acetato-κO:O')(μ(2)-acetic acid-κO:O')di-μ-aqua-copper(II)tris-odium].

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Di-μ-chlorido-bis-{[4-chloro-2-(dimethyl-amino-meth-yl)phenyl-κC,N]palladium(II)}.

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catena-Poly[[[(2-phenyl-acetato-κO)zinc(II)]bis-[μ-4,4'-(disulfanedi-yl)dipyridine-κN:N']] monohydrate].

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Bis(chloro-acetato-κO,O')bis-(2-fluoro-benzyl-κC)tin(IV).

Project description:In the title complex, [Sn(C(2)H(2)ClO(2))(2)(C(7)H(6)F)(2)], the Sn(IV) atom is located on a twofold rotation axis and forms a strongly distorted trans-octa-hedral geometry. The equatorial plane is defined by two chelating chloro-acetate ligands with asymmetrical Sn-O bond lengths, while the axial positions are occupied by the C atoms of two 2-fluoro-benzyl groups. In the crystal, infinite chains in the [010] direction are formed through inter-molecular Sn⋯O inter-actions [Sn⋯O separation = 3.682 (3) Å].

| S-EPMC3238784 | biostudies-literature

catena-Poly[[(1,10-phenanthroline-κN,N')praseodymium(III)]-di-μ-phenoxy-acetato-κO:O'-[(1,10-phenanthroline-κN,N')praseodymium(III)]-di-μ-phenoxy-acetato-κO:O'-di-μ-phenoxy-acetato-κO,O':O;κO:O,O'].

Project description:The title complex, [Pr(2)(C(8)H(7)O(3))(6)(C(12)H(8)N(2))(2)](n), which has an inversion centre midway between the two Pr(III) atoms of the structural unit, forms a one-dimensional polymer bridged alternately by either two bidentate, or two bidentate and two terdentate, phenoxy-acetate carboxyl-ate groups. Each Pr(III) atom is thus nine-coordinated by two N atoms of a 1,10-phenanthroline ligand and seven O atoms from six phenoxy-acetate ligands. The coordination geometry at the Pr(III) atom is distorted tricapped trigonal prismatic. One phenyl ring is disordered over two positions; the site occupancy factors are ca 0.6 and 0.4.

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