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Bis[2-phenyl-1-(phenyl-iminio)isoindo-line] di-?-chlorido-bis-[dichloridopalladate(II)] benzene disolvate.

ABSTRACT: In the title compound, (C(20)H(17)N(2))(2)[Pd(2)Cl(6)]·2C(6)H(6), the dichloride-bridged [Pd(2)Cl(6)](2-) anion lies across an inversion center with each Pd(II) ion in a slightly distorted square-planar environment. In the crystal structure, two cations and an anion are connected via N-H?Cl hydrogen bonds between the NH groups of the iminioisoindoline cations and terminal Cl atoms of a hexa-chloridodipalladate(II) anion. The Pd-Cl distance of the terminal chloride engaged in hydrogen bonding is slightly longer than the Pd-Cl distance of the adjacent terminal chloride which is not involved in hydrogen bonding.

SUBMITTER: Chitanda JM

PROVIDER: S-EPMC2961759 | biostudies-literature | 2008 Jun

REPOSITORIES: biostudies-literature

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Bis[2-phenyl-1-(phenyl-iminio)isoindo-line] di-μ-chlorido-bis-[dichloridopalladate(II)] benzene disolvate.

Chitanda Jackson M JM Quail J Wilson JW Foley Stephen R SR

Acta crystallographica. Section E, Structure reports online 20080613 Pt 7

In the title compound, (C(20)H(17)N(2))(2)[Pd(2)Cl(6)]·2C(6)H(6), the dichloride-bridged [Pd(2)Cl(6)](2-) anion lies across an inversion center with each Pd(II) ion in a slightly distorted square-planar environment. In the crystal structure, two cations and an anion are connected via N-H⋯Cl hydrogen bonds between the NH groups of the iminioisoindoline cations and terminal Cl atoms of a hexa-chloridodipalladate(II) anion. The Pd-Cl distance of the terminal chloride engaged in hydrogen bonding is ...[more]

PMID: 21202770

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