Unknown

Dataset Information

0

{1,8-Bis[2-(2-oxidobenzyl-idene-amino)phen-oxy]-3,6-dioxaocta-ne}nitrato-praseodymium(III) trichloro-methane solvate.


ABSTRACT: In the title compound, [Pr(C(32)H(30)N(2)O(6))(NO(3))]·CHCl(3), the Pr(III) ion is ten-coordinated by eight O atoms and two N atoms from the acyclic crown-type Schiff base ligand and the bidentate nitrate group. The coordination polyhedron around Pr(III) is a distorted bicapped square anti-prism. The chloro-form solvent mol-ecule is not involved either in coordination to the Pr(III) center or in hydrogen bonding to the complex. The Pr-O(phenolate) bonds are significantly shorter than the Pr-O(ether) and Pr-O(nitrate) bonds, which suggests that the Pr-O(phenolate) bond is stronger than these other bonds. In the crystal structure, the acyclic crown-type Schiff base ligand wraps around the Pr(III) centre, forming a pseudo-ring.

SUBMITTER: Liu WS 

PROVIDER: S-EPMC2961995 | biostudies-literature |

REPOSITORIES: biostudies-literature

Similar Datasets

| S-EPMC2959948 | biostudies-literature
| S-EPMC2968428 | biostudies-literature
| S-EPMC2983609 | biostudies-literature
| S-EPMC3414312 | biostudies-literature
| S-EPMC3007043 | biostudies-literature
| S-EPMC2960331 | biostudies-literature
| S-EPMC2969555 | biostudies-literature
| S-EPMC2972125 | biostudies-literature
| S-EPMC3295487 | biostudies-literature
| S-EPMC2979913 | biostudies-literature