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Bis{4-[(3-phenyl-allyl-idene)amino]cyclo-hexyl}methane trichloro-methane solvate.

ABSTRACT: The title compound, C(31)H(38)N(2), was prepared from bis-(4-amino-cyclo-hexyl)methane and two equivalents of cinnamaldehyde. The cyclo-hexyl groups each show a chair conformation and the α,β-unsaturated imine side chains are all-trans configured. Two mol-ecules of the title compound as well as two trichloromethane solvent mol-ecules are present in the asymmetric unit. The solvent mol-ecules inter-act with the diimines via weak C-H⋯N hydrogen bonds.

SUBMITTER: Menzel R

PROVIDER: S-EPMC2959948 | biostudies-literature |

REPOSITORIES: biostudies-literature

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{1,8-Bis[2-(2-oxidobenzyl-idene-amino)phen-oxy]-3,6-dioxaocta-ne}nitrato-praseodymium(III) trichloro-methane solvate.

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Bis(2-cyclo-hexyl-imino-methyl-4,6-disulfanylphenolato)nickel(II) acetonitrile solvate.

Project description:In the title compound, [Ni(C(13)H(16)NOS(2))(2)]·CH(3)CN, the Ni(II) atom is four-coordinated by two N,O-bidentate Schiff base ligands, resulting in a distorted tetra-hedral coordination for the metal ion.

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Project description:In the title compound, C(6)H(19)N(4) (+)·Cl(-)·CH(2)Cl(2), the non-H atoms of the ammonium ion show non-crystallographic C(3) symmetry. The chloride ion is embedded in a framework of seven crystallographically independent hydrogen bonds (five N-H?Cl and two C-H?Cl), which form layers parallel to the (100) plane. Two N---H...N bonds also occur.

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Project description:In the title Schiff base, C(30)H(24)N(2), the complete molecule is generated by a crystallographic twofold axis; the aromatic rings of the biphenyl unit are twisted by 60.78?(1)°. The imine double bond has a trans configuration.

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Crystal structure of bis-(cyclo-hexyl-ammonium) di-phenyl-dioxalatostannate(IV).

Project description:Reaction of oxalic acid and di-phenyl-tin dichloride in the presence of cyclo-hexyl-amine led to the formation of the title salt, (C6H14N)2[Sn(C6H5)2(C2O4)2]. The dianion is made up from an Sn(C6H5)2 moiety cis-coordinated by two chelating oxalate anions, leading to an overall distorted octa-hedral coordination geometry of the Sn(IV) atom. The negative charges are compensated by two surrounding cyclo-hexyl-ammonium cations adopting chair conformations each. In the crystal, anions and cations are linked via a network of N-H?O hydrogen bonds into a layered arrangement parallel to (101).

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Project description:In the title compound, C(14)H(19)N(3)S, the cyclo-hexane ring has a chair conformation. The almost planar amino-thio-urea unit (r.m.s. deviation = 0.0062?Å) is aligned at a dihedral angle of 45.23?(8)° with respect to the benzene ring. Inter-molecular N-H?N and N-H?S hydrogen bonding stabilizes the crystal structure.

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Crystal structure of 3-benzyl-1-[(cyclo-hexyl-idene)amino]-thio-urea.

Project description:The conformation of the title compound, C14H19N3S, is partially determined by an intra-molecular N-H⋯N hydro-gen-bond inter-action, although the N-H⋯N angle of 108° is quite small. The cyclo-hexyl-idene ring has a chair conformation and its mean plane is inclined to the benzene ring by 46.30 (8)°. In the crystal, mol-ecules are linked by pairs of N-H⋯S hydrogen bonds, forming inversion dimers, with an R 2 (2)(8) ring motif. The dimers are reinforced by pairs of C-H⋯S hydrogen bonds, and are linked by further weak C-H⋯S hydrogen bonds, forming chains propagating along [100].

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Bis[dicyclo-hexyl-(phenyl)-phosphane-κP]silver(I) perchlorate dichloro-methane monosolvate.

Project description:In the title compound, [Ag{P(C(6)H(11))(2)(C(6)H(5))}(2)]ClO(4)·CH(2)Cl(2), the Ag(I) atom in the mononuclear complex cation is coordinated by two P atoms of the phosphane ligands [Ag-P = 2.3993 (4) and 2.4011 (4) Å; P-Ag-P = 177.473 (18)°] and the perchlorate anion acts as the counter-anion. There is an Ag⋯O(perchlorate) inter-action of 2.873 (2) Å, which contributes to the slightly non-linear bond angle about the Ag(I) atom. Weak inter-molecular C-H⋯O hydrogen-bonding inter-actions involving phenyl, cyclo-hexyl and dichloro-methane H-atom donors and perchlorate O-atom acceptors contribute to the stabilization of the crystal structure.

| S-EPMC3099967 | biostudies-literature

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