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1-[2-(4-Fluoro-benz-yloxy)-2-phenyl-ethyl]-1H-benzimidazole.

ABSTRACT: The asymmetric unit of the title compound, C(22)H(19)FN(2)O, contains two independent mol-ecules. The planar benzimidazole ring systems are oriented with respect to the phen-yl/fluoro-benzene rings at dihedral angles of 31.10?(4)/45.17?(5) and 45.52?(5)/68.63?(5)°, respectively, for the two mol-ecules. In the crystal structure, inter-molecular C-H?N and inter-molecular C-H?N and C-H?F hydrogen bonds link the mol-ecules into a three-dimensional network. There are C-H?? contacts between the benzimidazole and fluoro-benzene rings and a ?-? contact between the benzimidazole and phenyl ring systems [centroid-centroid distance = 4.575?(1)?Å].

SUBMITTER: Ozel Guven O 

PROVIDER: S-EPMC2962126 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

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1-[2-(4-Fluoro-benz-yloxy)-2-phenyl-ethyl]-1H-benzimidazole.

Ozel Güven Ozden O   Erdoğan Taner T   Coles Simon J SJ   Hökelek Tuncer T  

Acta crystallographica. Section E, Structure reports online 20080716 Pt 8

The asymmetric unit of the title compound, C(22)H(19)FN(2)O, contains two independent mol-ecules. The planar benzimidazole ring systems are oriented with respect to the phen-yl/fluoro-benzene rings at dihedral angles of 31.10 (4)/45.17 (5) and 45.52 (5)/68.63 (5)°, respectively, for the two mol-ecules. In the crystal structure, inter-molecular C-H⋯N and inter-molecular C-H⋯N and C-H⋯F hydrogen bonds link the mol-ecules into a three-dimensional network. There are C-H⋯π contacts between the benzim  ...[more]

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