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1,1,1,3,3,3-Hexafluoro-2,2-bis-[4-(4-nitro-phen-oxy)phen-yl]propane.

ABSTRACT: In the title compound, C(27)H(16)F(6)N(2)O(6), the nitro groups are almost coplanar with the aromatic rings to which they are attached [dihedral angles = 3.5?(5) and 6.2?(3)°]. The dihedral angles between adjacent aromatic rings are 78.07?(8) and 71.11?(8)° for nitro-phen-yl/phenyl and 69.50?(8)° for phen-yl/phenyl. An inter-molecular C-H?? inter-action seems to be effective in the stabilization of the structure.

SUBMITTER: Nawaz H

PROVIDER: S-EPMC2962162 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

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1,1,1,3,3,3-Hexafluoro-2,2-bis-[4-(4-nitro-phen-oxy)phen-yl]propane.

Nawaz H H Akhter Zareen Z Bolte Michael M Butt M S MS Siddiqi Humaira M HM

Acta crystallographica. Section E, Structure reports online 20080719 Pt 8

In the title compound, C(27)H(16)F(6)N(2)O(6), the nitro groups are almost coplanar with the aromatic rings to which they are attached [dihedral angles = 3.5 (5) and 6.2 (3)°]. The dihedral angles between adjacent aromatic rings are 78.07 (8) and 71.11 (8)° for nitro-phen-yl/phenyl and 69.50 (8)° for phen-yl/phenyl. An inter-molecular C-H⋯π inter-action seems to be effective in the stabilization of the structure. ...[more]

PMID: 21203242

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