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1,3-Bis(2,3,5,6-tetra-fluoro-4-iodo-phen-oxy)-2,2-bis-[(2,3,5,6-tetra-fluoro-4-iodo-phen-oxy)meth-yl]propane.

ABSTRACT: In the crystal structure of the title compound, C29H8F16I4O4, short I?I and I?F contacts, which can be understood as halogen bonds (XBs), represent the strongest inter-molecular inter-actions, consistent with the presence of I and F atoms, and the absence of H atoms, at the periphery of the mol-ecule. In addition, ?-? stacking inter-actions between tetra-fluoro-iodo-phenyl (TFIP) groups and five short F?F inter-actions are present.

SUBMITTER: Cavallo G

PROVIDER: S-EPMC3629626 | biostudies-literature | 2013 Apr

REPOSITORIES: biostudies-literature

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1,3-Bis(2,3,5,6-tetra-fluoro-4-iodo-phen-oxy)-2,2-bis-[(2,3,5,6-tetra-fluoro-4-iodo-phen-oxy)meth-yl]propane.

Cavallo Gabriella G Metrangolo Pierangelo P Pilati Tullio T Resnati Giuseppe G Terraneo Giancarlo G Ursini Maurizio M

Acta crystallographica. Section E, Structure reports online 20130323 Pt 4

In the crystal structure of the title compound, C29H8F16I4O4, short I⋯I and I⋯F contacts, which can be understood as halogen bonds (XBs), represent the strongest inter-molecular inter-actions, consistent with the presence of I and F atoms, and the absence of H atoms, at the periphery of the mol-ecule. In addition, π-π stacking inter-actions between tetra-fluoro-iodo-phenyl (TFIP) groups and five short F⋯F inter-actions are present. ...[more]

PMID: 23634113

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