Unknown

Dataset Information

0

(2S,NS)-N-Allyl-N-benzyl-1-hydr-oxy-3-(4-hydroxy-phen-yl)-N-methyl-propan-2-aminium bromide.

ABSTRACT: The title compound, C(20)H(26)NO(2) (+)·Br(-), is an N-chiral quaternary ammonium salt synthesized from (2S*)-N-benzyl-N-methyl-tyrosine methyl ester. The dihedral angle between the phenyl ring and the benzene ring is 11.61?(19)°. In the crystal structure, the allyl group is disordered over two positions with site occupancy factors of ca 0.8 and 0.2. The bromide anion links to the quaternary ammonium cations via O-H?Br hydrogen bonding. An intramolecular O-H?Br hydrogen bond is also observed.

SUBMITTER: Wu HF 

PROVIDER: S-EPMC2962230 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

(2S,NS)-N-Allyl-N-benzyl-1-hydr-oxy-3-(4-hydroxy-phen-yl)-N-methyl-propan-2-aminium bromide.

Wu Hua-Fang HF   Luo Ying-Gang YG   Yu Kai-Bei KB   Zhang Guo-Lin GL   Pan Xin-Fu XF  

Acta crystallographica. Section E, Structure reports online 20080731 Pt 8

The title compound, C(20)H(26)NO(2) (+)·Br(-), is an N-chiral quaternary ammonium salt synthesized from (2S*)-N-benzyl-N-methyl-tyrosine methyl ester. The dihedral angle between the phenyl ring and the benzene ring is 11.61 (19)°. In the crystal structure, the allyl group is disordered over two positions with site occupancy factors of ca 0.8 and 0.2. The bromide anion links to the quaternary ammonium cations via O-H⋯Br hydrogen bonding. An intramolecular O-H⋯Br hydrogen bond is also observed. ...[more]

Similar Datasets

Unknown 3-Dodec-yloxy-2-hydr-oxy-N,N,N-trimethyl-propan-1-aminium bromide.
| S-EPMC2977172 | biostudies-literature
Unknown 3-Hydr-oxy-N'-(2-hydroxy-benzyl-idene)benzohydrazide.
| S-EPMC2959272 | biostudies-literature
Unknown 1,3-Dihydr-oxy-2-(hydroxy-meth-yl)propan-2-aminium 2,2-dichloro-acetate.
| S-EPMC2969592 | biostudies-literature
Unknown 4-Hydr-oxy-N'-(3,5-dichloro-2-hydroxy-benzyl-idene)benzohydrazide.
| S-EPMC2969228 | biostudies-literature
Unknown (E)-3-Hydr-oxy-N'-(2-hydroxy-benzyl-idene)-2-naphthohydrazide.
| S-EPMC2980095 | biostudies-literature
Unknown (S)-1-Hydroxy-propan-2-aminium (2R,3R)-3-carb-oxy-2,3-dihydroxy-propanoate monohydrate.
| S-EPMC2960284 | biostudies-literature
Unknown Bis(propan-2-yl) [(2S,3S)-2-hydr-oxy-3-nitro-butan-2-yl]phospho-nate.
| S-EPMC2980212 | biostudies-literature
Unknown N'-(3-Eth-oxy-2-hydroxy-benzyl-idene)-4-hydr-oxy-3-methoxy-benzohydrazide monohydrate.
| S-EPMC2970457 | biostudies-literature
Unknown Monoclinic modification of N-benzyl-propan-2-aminium chloride.
| S-EPMC2979101 | biostudies-literature
Unknown N-Benzyl-propan-2-aminium chloride.
| S-EPMC2983519 | biostudies-other