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Triaqua-chlorido(1,10-phenanthroline-?N,N')cobalt(II) chloride monohydrate.

ABSTRACT: In the title compound, [CoCl(C(12)H(8)N(2))(H(2)O)(3)]Cl·H(2)O, the Co(II) ion is coordinated by two N atoms from the 1,10-phenanthroline ligand [Co-N = 2.125?(6) and 2.146?(6)?Å], one chloride ligand [Co-Cl = 2.459?(2)Å] and three water mol-ecules [Co-O = 2.070?(5)-2.105?(5)Å] in a distorted octa-hedral geometry. Inter-molecular O-H?Cl and O-H?O hydrogen bonds form an extensive three-dimensional hydrogen-bonding network, which consolidates the crystal packing.

SUBMITTER: Liu Y 

PROVIDER: S-EPMC2968016 | biostudies-literature | 2008 Dec

REPOSITORIES: biostudies-literature

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Triaqua-chlorido(1,10-phenanthroline-κN,N')cobalt(II) chloride monohydrate.

Liu Yaru Y   Pan Yutian Y   Sun Junshan J   Zhang Chuan C  

Acta crystallographica. Section E, Structure reports online 20081220 Pt 1

In the title compound, [CoCl(C(12)H(8)N(2))(H(2)O)(3)]Cl·H(2)O, the Co(II) ion is coordinated by two N atoms from the 1,10-phenanthroline ligand [Co-N = 2.125 (6) and 2.146 (6) Å], one chloride ligand [Co-Cl = 2.459 (2)Å] and three water mol-ecules [Co-O = 2.070 (5)-2.105 (5)Å] in a distorted octa-hedral geometry. Inter-molecular O-H⋯Cl and O-H⋯O hydrogen bonds form an extensive three-dimensional hydrogen-bonding network, which consolidates the crystal packing. ...[more]

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