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(5-Amino-isophthalato-?N)triaqua-(1,10-phenanthroline-?N,N')nickel(II) trihydrate.

ABSTRACT: The Ni(II) atom in the title compound, [Ni(C(8)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)(3)]·3H(2)O, is six-coordinated in an NiN(3)O(3) octa-hedral geometry. The triply water-coordinated Ni(II) atom is chelated by the phenantroline ligand and is additionally coordinated by the amino group of the 5-amino-isophtalate anion. The anion, the coordinated and the uncoordinated water mol-ecules inter-act through an extensive O-H?O and N-H?O hydrogen-bonding network, generating a three-dimensional cage-like network.

SUBMITTER: Huang H 

PROVIDER: S-EPMC3099854 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

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(5-Amino-isophthalato-κN)triaqua-(1,10-phenanthroline-κN,N')nickel(II) trihydrate.

Huang Han H   Zhang Kou-Lin KL   Ng Seik Weng SW  

Acta crystallographica. Section E, Structure reports online 20110315 Pt 4

The Ni(II) atom in the title compound, [Ni(C(8)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)(3)]·3H(2)O, is six-coordinated in an NiN(3)O(3) octa-hedral geometry. The triply water-coordinated Ni(II) atom is chelated by the phenantroline ligand and is additionally coordinated by the amino group of the 5-amino-isophtalate anion. The anion, the coordinated and the uncoordinated water mol-ecules inter-act through an extensive O-H⋯O and N-H⋯O hydrogen-bonding network, generating a three-dimensional cage-like netw  ...[more]

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