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Triaqua-(1,10-phenanthroline-?N,N')(sulfato-?O)zinc(II).

ABSTRACT: The Zn(II) atom in the title compound, [Zn(SO(4))(C(12)H(8)N(2))(H(2)O)(3)], is coordinated by one O atom from a sulfate dianion, two N atoms from a 1,10-phenanthroline mol-ecule and three water O atoms in an octa-hedral geometry. An intra-molecular O-H?O hydrogen bond occurs. Inter-molecular O-H?O hydrogen bonds generate a layer structure parallel to (001). There are weak C-H?O inter-actions within the layers.

SUBMITTER: Liu H 

PROVIDER: S-EPMC3051486 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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Triaqua-(1,10-phenanthroline-κN,N')(sulfato-κO)zinc(II).

Liu Hong H   Qin Hui H   Zhang Yun-Jie YJ   Yang Hong-Wei HW   Zhang Jian J  

Acta crystallographica. Section E, Structure reports online 20110129 Pt 2

The Zn(II) atom in the title compound, [Zn(SO(4))(C(12)H(8)N(2))(H(2)O)(3)], is coordinated by one O atom from a sulfate dianion, two N atoms from a 1,10-phenanthroline mol-ecule and three water O atoms in an octa-hedral geometry. An intra-molecular O-H⋯O hydrogen bond occurs. Inter-molecular O-H⋯O hydrogen bonds generate a layer structure parallel to (001). There are weak C-H⋯O inter-actions within the layers. ...[more]

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