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Tris(2,2'-bipyridyl-?N,N')copper(II) sulfate 7.5-hydrate.

ABSTRACT: The title compound, [Cu(C(10)H(8)N(2))(3)]SO(4)·7.5H(2)O, is a six-coordinate copper(II) complex with a slightly elongated octa-hedral coordination geometry. The pyridyl rings of the three bipyridyl ligands are not coplanar, making dihedral angels of 9.5?(5), 5.2?(4) and 5.8?(5)°. In the crystal, several O-H?O and C-H?O hydrogen-bonding inter-actions are observed due to the existance of a large number of water mol-ecules and the sulfate dianions.

SUBMITTER: Xu F 

PROVIDER: S-EPMC2968254 | biostudies-literature | 2009 Jan

REPOSITORIES: biostudies-literature

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Tris(2,2'-bipyridyl-κN,N')copper(II) sulfate 7.5-hydrate.

Xu Feng F   You Wei W   Huang Wei W  

Acta crystallographica. Section E, Structure reports online 20090108 Pt 2

The title compound, [Cu(C(10)H(8)N(2))(3)]SO(4)·7.5H(2)O, is a six-coordinate copper(II) complex with a slightly elongated octa-hedral coordination geometry. The pyridyl rings of the three bipyridyl ligands are not coplanar, making dihedral angels of 9.5 (5), 5.2 (4) and 5.8 (5)°. In the crystal, several O-H⋯O and C-H⋯O hydrogen-bonding inter-actions are observed due to the existance of a large number of water mol-ecules and the sulfate dianions. ...[more]

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