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(2,2'-Bipyridyl-?N,N')chlorido(dl-threoninato-?N,O)copper(II) monohydrate.

ABSTRACT: In the title compound, [Cu(C(4)H(8)NO(3))Cl(C(10)H(8)N(2))]·H(2)O, the Cu(II) atom is in a slightly distorted square-pyramidal coordination geometry with the basal plane defined by the two N atoms of the bipyridine ligand and the N and O atoms from the threoninate ion and the apical site occupied by the Cl atom. In the crystal, inter-molecular O-H?O, N-H?O, O-H?Cl, C-H?O and C-H?Cl inter-actions link the mol-ecules into a three-dimensional network. A ?-? inter-action with a centroid-centroid distance of 3.461?(1)?Å is also present.

SUBMITTER: Tan YH

PROVIDER: S-EPMC3051714 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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(2,2'-Bipyridyl-κN,N')chlorido(dl-threoninato-κN,O)copper(II) monohydrate.

Tan Yi-Han YH Teoh Siang-Guan SG Rosli Mohd Mustaqim MM Fun Hoong-Kun HK

Acta crystallographica. Section E, Structure reports online 20110126 Pt 2

In the title compound, [Cu(C(4)H(8)NO(3))Cl(C(10)H(8)N(2))]·H(2)O, the Cu(II) atom is in a slightly distorted square-pyramidal coordination geometry with the basal plane defined by the two N atoms of the bipyridine ligand and the N and O atoms from the threoninate ion and the apical site occupied by the Cl atom. In the crystal, inter-molecular O-H⋯O, N-H⋯O, O-H⋯Cl, C-H⋯O and C-H⋯Cl inter-actions link the mol-ecules into a three-dimensional network. A π-π inter-action with a centroid-centroid dis ...[more]

PMID: 21522913

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