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Tetra-aqua-(2,2'-diamino-4,4'-bi-1,3-thia-zole-?N,N)nickel(II) bis-(pyridine-2,6-dicarboxyl-ato-?O,N,O)nickel(II) trihydrate.

ABSTRACT: The crystal structure of the title compound, [Ni(C(6)H(6)N(4)S(2))(H(2)O)(4)][Ni(C(7)H(3)NO(4))(2)]·3H(2)O, consists of Ni(II) complex cations, Ni(II) complex anions and lattice water mol-ecules. The Ni(II) ions in both the complex cation and anion assume a distorted octa-hedral coordination geometry. O-H?O, N-H?O and C-H?S hydrogen bonds occur in the crystal structure.

SUBMITTER: Liu BX

PROVIDER: S-EPMC2968453 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature

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Tetra-aqua-(2,2'-diamino-4,4'-bi-1,3-thia-zole-κN,N)nickel(II) bis-(pyridine-2,6-dicarboxyl-ato-κO,N,O)nickel(II) trihydrate.

Liu Bing-Xin BX Yu Yan-Ping YP Cao Zen Z Zhang Liang-Jun LJ

Acta crystallographica. Section E, Structure reports online 20090218 Pt 3

The crystal structure of the title compound, [Ni(C(6)H(6)N(4)S(2))(H(2)O)(4)][Ni(C(7)H(3)NO(4))(2)]·3H(2)O, consists of Ni(II) complex cations, Ni(II) complex anions and lattice water mol-ecules. The Ni(II) ions in both the complex cation and anion assume a distorted octa-hedral coordination geometry. O-H⋯O, N-H⋯O and C-H⋯S hydrogen bonds occur in the crystal structure. ...[more]

PMID: 21582064

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