Unknown

Dataset Information

0

Tetra-aqua-(2,2'-bipyridine-5,5'-dicarboxyl-ato-?N,N')nickel(II) dihydrate.

ABSTRACT: In the title compound, [Ni(C(12)H(6)N(2)O(4))(H(2)O)(4)]·2H(2)O, obtained from a basic solution of 2,2'-bipyridine-5,5'-dicarboxyl-ate and nickel(II) chloride in water, the central Ni(II) cation (site symmetry 2) is coordinated by two N atoms from the 2,2'-bipyridine-5,5'-dicarboxyl-ate ligand and four aqua O atoms. The N-Ni-N angle is 78.64?(8)°. Weak but significant ?-? stacking inter-actions exist between the pyridine rings with a centroid-centroid distance of 3.652?(8)?Å. In addition, four O atoms of the two carboxyl groups form hydrogen bonds with both coordinated and uncoordinated water mol-ecules, forming an infinite three-dimensional network.

SUBMITTER: Yang H 

PROVIDER: S-EPMC2970486 | biostudies-literature | 2009 Sep

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Tetra-aqua-(2,2'-bipyridine-5,5'-dicarboxyl-ato-κN,N')nickel(II) dihydrate.

Yang Hua H  

Acta crystallographica. Section E, Structure reports online 20090912 Pt 10

In the title compound, [Ni(C(12)H(6)N(2)O(4))(H(2)O)(4)]·2H(2)O, obtained from a basic solution of 2,2'-bipyridine-5,5'-dicarboxyl-ate and nickel(II) chloride in water, the central Ni(II) cation (site symmetry 2) is coordinated by two N atoms from the 2,2'-bipyridine-5,5'-dicarboxyl-ate ligand and four aqua O atoms. The N-Ni-N angle is 78.64 (8)°. Weak but significant π-π stacking inter-actions exist between the pyridine rings with a centroid-centroid distance of 3.652 (8) Å. In addition, four O  ...[more]

Similar Datasets

Unknown Poly[(?(5)-2,2'-bipyridine-5,5'-dicarboxyl-ato)lead(II)].
| S-EPMC3435613 | biostudies-literature
Unknown Diaqua-(2,2'-bipyridine-6,6'-dicarboxyl-ato)nickel(II).
| S-EPMC3120548 | biostudies-literature
Unknown Bis(?-naphthalene-1,8-dicarboxyl-ato)bis-[aqua-(2,2'-bipyridine)zinc(II)] tetra-hydrate.
| S-EPMC2959877 | biostudies-literature
Unknown Poly[[tetra-aqua-(?(6)-2,2'-diiodo-biphenyl-4,4',5,5'-tetra-carboxyl-ato)dizinc(II)] dihydrate].
| S-EPMC2960511 | biostudies-literature
Unknown Bis(?-biphenyl-2,2'-dicarboxyl-ato)bis-[aqua-(2,2'-bipyridine)cadmium(II)].
| S-EPMC2979598 | biostudies-literature
Unknown Synchrotron study of poly[[di-?-aqua-(?-2,2'-bipyridyl-5,5'-dicarboxyl-ato)di-potassium] dihydrate].
| S-EPMC2970491 | biostudies-literature
Unknown Tetra-aqua-(2,2'-bipyridine-?²N,N')nickel(II) sulfate.
| S-EPMC3393179 | biostudies-literature
Unknown Tetra-aqua-(5,5'-dimethyl-2,2'-bipyridine-?N,N')zinc(II) sulfate.
| S-EPMC2977444 | biostudies-literature
Unknown Bis(?-biphenyl-2,2'-dicarboxyl-ato)bis-[aqua-(4,4'-dimethyl-2,2'-bipyridine-?N,N')copper(II)].
| S-EPMC2971185 | biostudies-literature
Unknown Aqua-(2,2'-bipyrid-yl)(pyrazine-2,6-dicarboxyl-ato)nickel(II) 1.25-hydrate.
| S-EPMC2959726 | biostudies-literature