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Poly[aqua-bis(?-benzene-1,2-dicarboxyl-ato)ethano-ltetra-lithium].

ABSTRACT: In the crystal structure of the title compound [Li(4)(C(8)H(4)O(4))(2)(C(2)H(5)OH)(H(2)O)](n), there are four crystallographically independent metal centers each of which is coordinated by four O atoms. The benzene-1,2-dicarboxyl-ate groups act as bidentate-bridging ligands producing a two-dimensional coordination network parallel to the ab plane. The coordination polymer is further stabilized by coordination of water and ethanol mol-ecules by the Li(+) ions. Simultaneously, the water and ethanol mol-ecules are involved in O-H?O and C-H?? inter-actions.

SUBMITTER: Rodriguez-Cuamatzi P

PROVIDER: S-EPMC2968522 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature

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Poly[aqua-bis(μ-benzene-1,2-dicarboxyl-ato)ethano-ltetra-lithium].

Rodríguez-Cuamatzi Patricia P Tlahuext Hugo H Höpfl Herbert H

Acta crystallographica. Section E, Structure reports online 20090204 Pt 3

In the crystal structure of the title compound [Li(4)(C(8)H(4)O(4))(2)(C(2)H(5)OH)(H(2)O)](n), there are four crystallographically independent metal centers each of which is coordinated by four O atoms. The benzene-1,2-dicarboxyl-ate groups act as bidentate-bridging ligands producing a two-dimensional coordination network parallel to the ab plane. The coordination polymer is further stabilized by coordination of water and ethanol mol-ecules by the Li(+) ions. Simultaneously, the water and ethano ...[more]

PMID: 21582040

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